The experimental gas laws
Boyle, Charles and Gay-Lussac
Before the complete equation, three partial laws were discovered, each obtained by keeping one quantity constant.
Boyle-Mariotte's law (at constant temperature). Compress a gas, its pressure rises, and the product P·V stays constant:
T fixed : P · V = constant (if V is halved, P doubles)
P
|•
| •
| •._ curve P·V = const (hyperbola)
| •.._______
+------------------> V
Charles's law (at constant pressure). Heat a gas, it expands; the volume is proportional to the absolute temperature:
P fixed : V / T = constant (T in kelvins ; V increases with T)
Gay-Lussac's law (at constant volume). Heat a gas trapped in a fixed volume, its pressure climbs, proportional to temperature:
V fixed : P / T = constant (T in kelvins ; P increases with T)
These three laws say the same thing from three angles: P rises when you compress, V rises when you heat at fixed pressure, P rises when you heat at fixed volume. Each time, temperature is in kelvins — that is what makes the proportions exact.
The decisive step is to notice that these three laws can be united into a single one, valid when everything varies at once. That is the ideal gas law, which contains them all.

