Quantifying and Exploiting the Effect
Kinetic Energy and Stopping Potential
Einstein's relation E_c,max = hν − W₀ is that of a straight line. If we plot the maximum kinetic energy of the electrons as a function of the frequency of the light, we get:
E_c,max
^
| /
| / slope = h
| /
| /
0 +-----------•------------> ν
| /|
| / ν₀ (threshold frequency)
-W₀ ......•
Three direct readings: the slope of the line is h (the Planck constant, the same for all metals!); the intersection with the horizontal axis gives the threshold frequency ν₀; the extension of the line crosses the vertical axis at −W₀. A single experiment therefore gives h and the work function of the metal.
How do we measure E_c,max? We apply a voltage that slows down the electrons. We increase it up to the value U₀, the stopping potential, at which even the fastest electrons are stopped: the current drops to zero. Their kinetic energy is then exactly balanced:
E_c,max = e·U₀ (e = elementary charge)
So measuring a voltage is enough to know the energy of the electrons. By repeating this for several frequencies, Millikan plotted the line above and measured h with remarkable precision — confirming Einstein despite his own initial skepticism. Remember: frequency → energy (through the slope h), intensity → number.

